1 00:00:15,709 --> 00:00:13,910 with the advent of space technology new 2 00:00:18,080 --> 00:00:15,719 opportunities are emerging for 3 00:00:21,080 --> 00:00:18,090 scientific research with exciting 4 00:00:23,060 --> 00:00:21,090 applications in many fields to take 5 00:00:26,000 --> 00:00:23,070 advantage of this new era in space 6 00:00:27,800 --> 00:00:26,010 exploration basic research into the 7 00:00:30,220 --> 00:00:27,810 fundamental characteristics of the 8 00:00:32,889 --> 00:00:30,230 environment of space such as long-term 9 00:00:37,130 --> 00:00:32,899 microgravity and ultra-high vacuum 10 00:00:39,170 --> 00:00:37,140 should first be undertaken the purpose 11 00:00:41,330 --> 00:00:39,180 of the research presented in this video 12 00:00:44,000 --> 00:00:41,340 is to understand more clearly the 13 00:00:46,850 --> 00:00:44,010 effects of surface tension on fluid 14 00:00:49,760 --> 00:00:46,860 convection the predominance of surface 15 00:00:52,459 --> 00:00:49,770 tension effects over buoyancy effects is 16 00:00:55,160 --> 00:00:52,469 a unique characteristic of microgravity 17 00:00:58,099 --> 00:00:55,170 environments and is critically important 18 00:01:00,349 --> 00:00:58,109 to many microgravity applications such 19 00:01:04,039 --> 00:01:00,359 as material processing and fluid 20 00:01:06,590 --> 00:01:04,049 management the fluid system chosen for 21 00:01:09,380 --> 00:01:06,600 this study the liquid sessile droplet 22 00:01:11,840 --> 00:01:09,390 has been selected because among many 23 00:01:14,600 --> 00:01:11,850 fluid systems most affected by surface 24 00:01:16,640 --> 00:01:14,610 tension liquid droplets are particularly 25 00:01:20,660 --> 00:01:16,650 important to many industrial and 26 00:01:22,969 --> 00:01:20,670 biological processes evaporation induced 27 00:01:25,520 --> 00:01:22,979 surface tension effects on liquid 28 00:01:28,730 --> 00:01:25,530 droplets and their associated transport 29 00:01:31,149 --> 00:01:28,740 process can significantly enhance heat 30 00:01:33,679 --> 00:01:31,159 and mass transfer 31 00:01:36,710 --> 00:01:33,689 they are also critical to a wide range 32 00:01:39,260 --> 00:01:36,720 of technologies such as single crystal 33 00:01:41,990 --> 00:01:39,270 growth the spray drying and cooling of 34 00:01:44,649 --> 00:01:42,000 metal and the advanced droplet radiators 35 00:01:47,690 --> 00:01:44,659 of the space stations power systems 36 00:01:50,359 --> 00:01:47,700 while quantitative research on surface 37 00:01:51,830 --> 00:01:50,369 tension induced flow is pivotal to our 38 00:01:54,469 --> 00:01:51,840 understanding of the microgravity 39 00:01:57,800 --> 00:01:54,479 environment it is difficult to achieve 40 00:01:59,929 --> 00:01:57,810 on earth not only do surface tension 41 00:02:02,569 --> 00:01:59,939 driven flow phenomena take place solely 42 00:02:04,429 --> 00:02:02,579 in small-scale systems under normal 43 00:02:07,550 --> 00:02:04,439 gravity surface tension properties 44 00:02:09,699 --> 00:02:07,560 themselves are very easily disturbed by 45 00:02:13,190 --> 00:02:09,709 experimental observation 46 00:02:15,559 --> 00:02:13,200 thus computational simulations 47 00:02:18,140 --> 00:02:15,569 offer an attractive way to investigate 48 00:02:21,110 --> 00:02:18,150 internal convection within liquid 49 00:02:23,360 --> 00:02:21,120 droplets during this video a 50 00:02:25,880 --> 00:02:23,370 cross-sectional representation of the 51 00:02:29,089 --> 00:02:25,890 hemispherical liquid droplet under ideal 52 00:02:32,990 --> 00:02:29,099 conditions is used to show internal 53 00:02:35,300 --> 00:02:33,000 fluid motion the droplet is placed on an 54 00:02:37,910 --> 00:02:35,310 unheated plate with evaporation 55 00:02:40,009 --> 00:02:37,920 occurring along the free surface the 56 00:02:43,280 --> 00:02:40,019 black dots within the liquid droplet are 57 00:02:46,490 --> 00:02:43,290 fluid tracers used to visualize fluid 58 00:02:50,210 --> 00:02:46,500 flow because the processes that occur 59 00:02:52,339 --> 00:02:50,220 are assumed symmetric with respect to 60 00:02:54,770 --> 00:02:52,349 the centerline we will be describing 61 00:02:58,699 --> 00:02:54,780 only the flow field in the right half of 62 00:03:01,250 --> 00:02:58,709 the droplet two types of evaporation 63 00:03:03,920 --> 00:03:01,260 induced convection are presented one 64 00:03:06,470 --> 00:03:03,930 under normal gravity where buoyancy is 65 00:03:09,199 --> 00:03:06,480 the most significant force the other 66 00:03:11,930 --> 00:03:09,209 under microgravity where buoyancy force 67 00:03:15,500 --> 00:03:11,940 subsides and surface tension effects 68 00:03:17,140 --> 00:03:15,510 predominate the patterns of flow that 69 00:03:20,050 --> 00:03:17,150 described them were obtained 70 00:03:23,210 --> 00:03:20,060 computationally using an Adi scheme 71 00:03:25,879 --> 00:03:23,220 while a runga cotta scheme tracks the 72 00:03:28,160 --> 00:03:25,889 motion of the fluid tracers the 73 00:03:34,430 --> 00:03:28,170 calculations required about one hour of 74 00:03:36,559 --> 00:03:34,440 CPU time on the Cray XMP 24in buoyancy 75 00:03:39,410 --> 00:03:36,569 induced convection otherwise known as 76 00:03:43,210 --> 00:03:39,420 Rayleigh convection gravity is the 77 00:03:46,039 --> 00:03:43,220 dominant force in stratified fluids 78 00:03:49,190 --> 00:03:46,049 stability exists when heavier fluids 79 00:03:51,140 --> 00:03:49,200 live beneath lighter fluids that is why 80 00:03:53,660 --> 00:03:51,150 when a heavier fluid lies above a 81 00:03:56,210 --> 00:03:53,670 lighter one the heavier fluid will tend 82 00:03:59,000 --> 00:03:56,220 to descend when the criteria for 83 00:04:03,220 --> 00:03:59,010 stability are exceeded the result will 84 00:04:06,440 --> 00:04:03,230 be fluid motion induced by gravity we 85 00:04:08,750 --> 00:04:06,450 begin with a liquid droplet having a 86 00:04:11,240 --> 00:04:08,760 uniform temperature shown in orange 87 00:04:14,150 --> 00:04:11,250 which is the same as the plate upon 88 00:04:16,759 --> 00:04:14,160 which it rests as evaporative cooling 89 00:04:19,150 --> 00:04:16,769 occurs along the free surface of the 90 00:04:22,009 --> 00:04:19,160 drop the temperature of that surface 91 00:04:26,600 --> 00:04:22,019 decreases which makes the fluid there 92 00:04:29,450 --> 00:04:26,610 heavier as evaporation proceeds the 93 00:04:32,029 --> 00:04:29,460 temperature continues to decrease and a 94 00:04:35,209 --> 00:04:32,039 yellow rim representing the colder fluid 95 00:04:37,490 --> 00:04:35,219 at the surface broadens eventually as 96 00:04:41,240 --> 00:04:37,500 the fluid turns even colder the rim 97 00:04:44,240 --> 00:04:41,250 becomes green and then blue as this 98 00:04:46,580 --> 00:04:44,250 increasingly heavier fluid descends the 99 00:04:49,760 --> 00:04:46,590 relatively warmer fluid of the interior 100 00:04:53,209 --> 00:04:49,770 ascends setting up a clockwise fluid 101 00:04:56,450 --> 00:04:53,219 convection because buoyancy force is a 102 00:04:59,209 --> 00:04:56,460 body force it induces a global motion 103 00:05:02,689 --> 00:04:59,219 and convection occurs almost everywhere 104 00:05:05,089 --> 00:05:02,699 within the liquid drop after an 105 00:05:08,330 --> 00:05:05,099 initially rapid flow the rate of 106 00:05:10,010 --> 00:05:08,340 convection gradually slows down as the 107 00:05:12,920 --> 00:05:10,020 temperature field becomes vertically 108 00:05:15,409 --> 00:05:12,930 more stable the clockwise fluid motion 109 00:05:18,350 --> 00:05:15,419 in the upper layer is reduced and it 110 00:05:26,390 --> 00:05:18,360 almost still predominantly lateral 111 00:05:28,790 --> 00:05:26,400 motion results eventually however as 112 00:05:30,730 --> 00:05:28,800 evaporative cooling continues to reduce 113 00:05:33,680 --> 00:05:30,740 the temperature at the surface a 114 00:05:37,159 --> 00:05:33,690 coupling between internal convection and 115 00:05:38,439 --> 00:05:37,169 that cooling induces to thermal 116 00:05:41,450 --> 00:05:38,449 stratifications 117 00:05:44,200 --> 00:05:41,460 the first stratification moves clockwise 118 00:05:47,659 --> 00:05:44,210 at the lower edge of the droplet surface 119 00:05:49,999 --> 00:05:47,669 the second moves counterclockwise and 120 00:05:52,790 --> 00:05:50,009 begins at the top of the surface as 121 00:05:56,059 --> 00:05:52,800 another vortex of cooler fluid moves 122 00:05:58,339 --> 00:05:56,069 downward into the interior demonstrating 123 00:06:03,159 --> 00:05:58,349 that evaporation induced buoyancy 124 00:06:06,709 --> 00:06:03,169 convection is a dynamic unsteady process 125 00:06:09,110 --> 00:06:06,719 unlike buoyancy dominant flow surface 126 00:06:12,469 --> 00:06:09,120 tension dominant flow has not been well 127 00:06:15,010 --> 00:06:12,479 studied however we do know that it is 128 00:06:19,579 --> 00:06:15,020 partly a function of temperature and 129 00:06:21,649 --> 00:06:19,589 concentration the present study focuses 130 00:06:24,800 --> 00:06:21,659 on the effect of temperature on surface 131 00:06:28,129 --> 00:06:24,810 tension the warmer the fluid the weaker 132 00:06:30,379 --> 00:06:28,139 the surface tension and conversely the 133 00:06:34,129 --> 00:06:30,389 colder the fluid the stronger the 134 00:06:36,290 --> 00:06:34,139 surface tension again we begin with a 135 00:06:38,540 --> 00:06:36,300 liquid droplet having a uniform 136 00:06:40,310 --> 00:06:38,550 temperature which is the same as the 137 00:06:44,120 --> 00:06:40,320 plate upon which it rests 138 00:06:46,610 --> 00:06:44,130 as evaporative cooling occurs along the 139 00:06:49,310 --> 00:06:46,620 droplets free surface the temperature 140 00:06:52,100 --> 00:06:49,320 there decreases shown here by the 141 00:06:55,360 --> 00:06:52,110 broadening yellow rim and it's gradual 142 00:06:57,800 --> 00:06:55,370 transformation from yellow to green 143 00:07:00,200 --> 00:06:57,810 because the temperature at the bottom of 144 00:07:02,690 --> 00:07:00,210 the plate is still warm a temperature 145 00:07:05,060 --> 00:07:02,700 gradient begins to form where the plate 146 00:07:08,090 --> 00:07:05,070 meets the lower edge of the relatively 147 00:07:10,910 --> 00:07:08,100 colder droplet the surface tension is 148 00:07:13,540 --> 00:07:10,920 weakest near the warm plate but stronger 149 00:07:15,950 --> 00:07:13,550 at the colder surface as a result 150 00:07:18,560 --> 00:07:15,960 surface tension is able to pull the 151 00:07:21,500 --> 00:07:18,570 fluid upwards that is away from the 152 00:07:26,090 --> 00:07:21,510 plate and fluid viscosity transfers 153 00:07:28,190 --> 00:07:26,100 momentum into the interior conservation 154 00:07:31,820 --> 00:07:28,200 of mass dictates that a circular 155 00:07:34,640 --> 00:07:31,830 counterclockwise motion or vortex wraps 156 00:07:38,780 --> 00:07:34,650 cold fluid into the interior of the drop 157 00:07:41,750 --> 00:07:38,790 to form a cold pocket the end result is 158 00:07:44,300 --> 00:07:41,760 a self propelling process with a maximum 159 00:07:47,390 --> 00:07:44,310 velocity and the largest temperature 160 00:07:49,370 --> 00:07:47,400 gradient coupled in the cold pocket to 161 00:07:52,310 --> 00:07:49,380 maintain the surface tension induced 162 00:07:55,780 --> 00:07:52,320 fluid flow which pushes the vortex all 163 00:07:59,150 --> 00:07:55,790 the way up the droplets free surface 164 00:08:00,940 --> 00:07:59,160 let's compare our computational results 165 00:08:04,840 --> 00:08:00,950 with what we observe experimentally 166 00:08:08,120 --> 00:08:04,850 using laser shadowgraph 167 00:08:10,820 --> 00:08:08,130 traces of aluminum particles allow us to 168 00:08:14,660 --> 00:08:10,830 visualize evaporation induced convective 169 00:08:17,030 --> 00:08:14,670 patterns inside a chloroform drop a few 170 00:08:21,470 --> 00:08:17,040 seconds after it was placed on an 171 00:08:24,950 --> 00:08:21,480 isothermal plate for regions of flow can 172 00:08:28,100 --> 00:08:24,960 be identified region 1 located at the 173 00:08:31,130 --> 00:08:28,110 top of the drop is stagnant region 2 174 00:08:35,180 --> 00:08:31,140 consists of weak clockwise convection 175 00:08:37,300 --> 00:08:35,190 currents driven by buoyancy force region 176 00:08:41,540 --> 00:08:37,310 3 is composed of a few layers of 177 00:08:44,290 --> 00:08:41,550 hexagonal flow cells finally region 4 178 00:08:46,910 --> 00:08:44,300 has relatively stronger counterclockwise 179 00:08:49,520 --> 00:08:46,920 convection currents which according to 180 00:08:53,330 --> 00:08:49,530 our computational results are driven by 181 00:08:54,020 --> 00:08:53,340 surface tension since the liquid drop is 182 00:08:56,990 --> 00:08:54,030 a small 183 00:08:59,090 --> 00:08:57,000 system surface tension is expected to 184 00:09:01,820 --> 00:08:59,100 play a dominant role in the evaporation 185 00:09:05,150 --> 00:09:01,830 process and this is also what we observe 186 00:09:08,210 --> 00:09:05,160 experimentally as evaporation proceeds 187 00:09:10,160 --> 00:09:08,220 the weak buoyancy induced flow region 188 00:09:13,120 --> 00:09:10,170 shrinks while a counter clockwise 189 00:09:17,090 --> 00:09:13,130 surface tension flow in Region four 190 00:09:19,340 --> 00:09:17,100 displaces Region three upwards this is 191 00:09:21,110 --> 00:09:19,350 exactly the result we saw earlier in the 192 00:09:24,350 --> 00:09:21,120 graphical presentation of surface 193 00:09:26,990 --> 00:09:24,360 tension dominant convection thus the 194 00:09:30,430 --> 00:09:27,000 computational results qualitatively 195 00:09:33,590 --> 00:09:30,440 match the experimental results well 196 00:09:36,740 --> 00:09:33,600 however the observations also reveal a 197 00:09:38,870 --> 00:09:36,750 drawback of the experimental method not 198 00:09:41,180 --> 00:09:38,880 only is the stagnant nature of region 199 00:09:43,880 --> 00:09:41,190 one exaggerated by the particles of 200 00:09:46,160 --> 00:09:43,890 aluminum that accumulate there but the 201 00:09:49,180 --> 00:09:46,170 accumulation eventually destroys the 202 00:09:51,650 --> 00:09:49,190 surface tension properties altogether 203 00:09:54,620 --> 00:09:51,660 let's review the graphical presentation 204 00:09:57,530 --> 00:09:54,630 of buoyancy dominant and thermo 205 00:10:00,260 --> 00:09:57,540 capillary dominant convection using 206 00:10:02,330 --> 00:10:00,270 numerical methods the elapsed time 207 00:10:04,430 --> 00:10:02,340 during this segment of the video will 208 00:10:08,180 --> 00:10:04,440 more accurately reflect real time 209 00:10:10,850 --> 00:10:08,190 processes in buoyancy dominant 210 00:10:14,030 --> 00:10:10,860 convection gravity is the dominant force 211 00:10:16,540 --> 00:10:14,040 as evaporation occurs the temperature at 212 00:10:19,580 --> 00:10:16,550 the droplet surface decreases a 213 00:10:22,060 --> 00:10:19,590 clockwise convection results as the 214 00:10:25,180 --> 00:10:22,070 increasingly colder and heavier fluid 215 00:10:28,190 --> 00:10:25,190 descends and the relatively warmer fluid 216 00:10:30,800 --> 00:10:28,200 ascends eventually as the rate of 217 00:10:33,740 --> 00:10:30,810 convection slows down the clockwise 218 00:10:36,470 --> 00:10:33,750 fluid motion is reduced and lateral 219 00:10:42,860 --> 00:10:36,480 motion predominates until a second 220 00:10:45,080 --> 00:10:42,870 counter clockwise motion begins when we 221 00:10:47,210 --> 00:10:45,090 observe the surface tension dominant 222 00:10:49,880 --> 00:10:47,220 flow characteristics of microgravity 223 00:10:52,850 --> 00:10:49,890 environments a different pattern of 224 00:10:54,920 --> 00:10:52,860 convection occurs the resulting fluid 225 00:10:57,230 --> 00:10:54,930 motion is generated by the surface 226 00:11:00,140 --> 00:10:57,240 tension gradient along the droplet 227 00:11:03,590 --> 00:11:00,150 surface which pulls the fluid upward in 228 00:11:06,200 --> 00:11:03,600 a circular counterclockwise motion the 229 00:11:07,940 --> 00:11:06,210 end result is a self propelling process 230 00:11:10,490 --> 00:11:07,950 with velocity and ten 231 00:11:14,750 --> 00:11:10,500 coupled to maintain the surface tension 232 00:11:16,940 --> 00:11:14,760 induced flow in this video we have seen 233 00:11:20,060 --> 00:11:16,950 a direct simulation of natural 234 00:11:22,970 --> 00:11:20,070 convection inside liquid droplets caused 235 00:11:24,920 --> 00:11:22,980 by evaporative cooling of the two 236 00:11:27,470 --> 00:11:24,930 mechanisms that induce convection 237 00:11:30,200 --> 00:11:27,480 the first was gravitational buoyancy 238 00:11:33,050 --> 00:11:30,210 force and the resulting fluid transport 239 00:11:35,510 --> 00:11:33,060 the well studied rayleigh natural 240 00:11:37,310 --> 00:11:35,520 convection the other mechanism which is 241 00:11:39,560 --> 00:11:37,320 less familiar to the thermal fluid 242 00:11:42,860 --> 00:11:39,570 society but more relevant to future 243 00:11:45,320 --> 00:11:42,870 space venture is surface tension induced 244 00:11:48,350 --> 00:11:45,330 by a thermal gradient and the resulting 245 00:11:51,680 --> 00:11:48,360 fluid motion the so called Marangoni or 246 00:11:53,420 --> 00:11:51,690 thermo capillary convection the 247 00:11:55,340 --> 00:11:53,430 fundamental difference is between these 248 00:11:59,210 --> 00:11:55,350 two convection patterns can be briefly 249 00:12:02,300 --> 00:11:59,220 summarized as follows gravitational 250 00:12:05,150 --> 00:12:02,310 buoyancy force is a body force thus the 251 00:12:07,340 --> 00:12:05,160 induced fluid dynamics is global and the 252 00:12:10,940 --> 00:12:07,350 resulting temperature field in the fluid 253 00:12:13,460 --> 00:12:10,950 is more homogeneous li mixed thermo 254 00:12:16,130 --> 00:12:13,470 capillary force is a surface force and 255 00:12:18,290 --> 00:12:16,140 here both the induced fluid motion and 256 00:12:23,210 --> 00:12:18,300 the thermal stratification is more 257 00:12:26,090 --> 00:12:23,220 intensified along the free surface under 258 00:12:27,980 --> 00:12:26,100 conditions of decreasing gravity the 259 00:12:30,070 --> 00:12:27,990 pattern of fluid flow will gradually 260 00:12:33,410 --> 00:12:30,080 become less dominated by buoyancy 261 00:12:35,320 --> 00:12:33,420 convection eventually when the force of 262 00:12:37,940 --> 00:12:35,330 gravity has been reduced significantly 263 00:12:42,980 --> 00:12:37,950 the flow pattern will be dominated by 264 00:12:44,840 --> 00:12:42,990 surface tension this research video has 265 00:12:47,240 --> 00:12:44,850 illustrated the clear differences 266 00:12:50,150 --> 00:12:47,250 between two mechanisms of fluid 267 00:12:53,750 --> 00:12:50,160 transport thermo capillary convection 268 00:12:56,330 --> 00:12:53,760 and buoyancy dominant convection in the 269 00:12:58,730 --> 00:12:56,340 future the investigator will expand his 270 00:13:00,980 --> 00:12:58,740 studies of fluid flow to explore the 271 00:13:03,860 --> 00:13:00,990 effects of surface tension on double 272 00:13:07,490 --> 00:13:03,870 diffusion and two phase related problems 273 00:13:09,140 --> 00:13:07,500 such as crystal growth he will also 274 00:13:11,330 --> 00:13:09,150 explore the potential of thermo 275 00:13:13,610 --> 00:13:11,340 capillary convection for the droplet 276 00:13:16,960 --> 00:13:13,620 radiators involved in the Space 277 00:13:19,400 --> 00:13:16,970 Station's power system such 278 00:13:21,740 --> 00:13:19,410 computational studies are laying the 279 00:13:24,070 --> 00:13:21,750 groundwork that will enable NASA 280 00:13:27,140 --> 00:13:24,080 and its partners in academia and 281 00:13:30,080 --> 00:13:27,150 industry to design the expensive 282 00:13:34,340 --> 00:13:30,090 experimental ventures in outer space of 283 00:13:36,740 --> 00:13:34,350 the coming decade together numerical and 284 00:13:38,900 --> 00:13:36,750 experimental studies we'll be able to 285 00:13:41,270 --> 00:13:38,910 meet the challenge of exploiting the 286 00:13:43,790 --> 00:13:41,280 revolutionary capabilities the space 287 00:13:46,550 --> 00:13:43,800 station offers thus helping to fulfill